densidade da gasolina

8/15/2019 Densidade Da Gasolina

1/15

UNIVERSIDADE TECNOLÓGICA FEDERALDO PARANÁ

PR

UNIVERSIDADE TECNOLÓGICA FEDERAL DO PARANÁCOORDENAÇÃO DE ENGENHARIA QUÍMICA

CÂMPUS APUCARANA

FRANCIELI CAROLINA SOUZA RIBEIRO

JAQUELINE CALODINO

ESTEVÃO R.

MARIA VITÓRIA

GUILHERME GONÇALVES

ESTUDOS DE ÁLCOOLS E FENÓIS

DETERMINAÇÃO DO TEOR DE ÁLCOOL E DENSIDADE DA GASOLINA


2/15

APUCARANA/PR

JUNHO DE 201FRANCIELI CAROLINA SOUZA RIBEIRO

JAQUELINE CALODINO

ESTEVÃO R.

MARIA VITÓRIA

GUILHERME GONÇALVES

ESTUDOS DE ÁLCOOLS E FENÓIS

DETERMINAÇÃO DO TEOR DE ÁLCOOL E DENSIDADE DA GASOLINA

R!"#$%&'( #)&!*!+$#,( - ,(!+$! ,( &*( ,!

E+!+#&'# Q3'# ,# U+'4!&*',#,!

T!+("%'# F!,!" ,( P#+5 (3( &!6'*'$(

)# (7$!+89( ,! +($# )#&'#" ,# ,'*')"'+# ,!

Q3'# (&:+'# 1.

P&(;


3/15

APUCARANA/PR

JUNHO DE 201

SUMÁRIO

1. INTRODUÇÃO........................................................................................................12. OBJETIVO..............................................................................................................==. MATERIAIS E M>TODOS......................................................................................=

=.1. MATERIAIS......................................................................................................==.2. M>TODOS.......................................................................................................=

?. RESULTADO E DISCUSS@ES..............................................................................?. CONCLUS@ES.......................................................................................................

. REFERNCIAS......................................................................................................


4/15

1. INTRODUÇÃO

N( ;!+(" ( &)( ',&('"# "'#*! ,'&!$#3!+$! # 3 #+!" #&(35$'( 3 *%"',(3("!"#& 7+( ! &'*$#"'+( (7$',( #+$'#3!+$! )(& ,!*$'"#89( ,( #"#$&9( ,!

"# 3#'* #$#"3!+$! *'+$!$'#,( # )#&$'& ,( 7!+!+( ATINS ! JONES 200K.

M'$(* ;!+%'* *7*$'$,(* ((&&!3 +# +#$&!# #"+* *!+,( &!*)(+*54!'* )!"#*

;&:+'#* ,! )"#+$#* *!+,( (3 ;&!6+'# (3)(+!+$! ,(* %"!(* !**!+'#'* '*$(

%"!(* (7$',(* )(& ,!*$'"#89( ,! ;"(&!* ( ;("#*. O $'3(" ( '+&!,'!+$! #$'4( ,(

(&#+( ! ( !!+(" ( )&'+')#" &!*)(+*54!" )!"( (,(& ! ( *#7(& ,( %"!( ,! (

ATINS ! JONES 200K.

O* ;!+%'* ,';!&!3 ,(* #"(%'* )(& *!&!3 5',(* ;(* )('* # &!**(+:+'# ,(

:+'(+ ,!*"(#"'# # #&# +!#$'4# ,# 7#*! (+#,# ,( ;!+(" ! !*$#7'"'# ( :+'(+.

C(3( &!*"$#,( ( :+'(+ 3# 7#*! (+#,# 3#'* ;# ,( 6! #* 7#*!* ,(*

#"(%'* (+*!6!+$!3!+$! ( ;!+(" 3 5',( 3#'* ;(&$! ,( 6! ( !$#+(" *!+,(

'+*("4!'* !3 5# ! *("4!'* !3 *("8!* 75*'#* ATINS ! JONES 200K.

U3 5"((" 3 (3)(*$( (&:+'( 6! (+$3 3 &)( ',&('"# 6! +9(

!*$5 ,'&!$#3!+$! "'#,( #( #+!" ,! 7!+!+( ( # 3 &)( CO. U3 ,(*

(3)(*$(* (&:+'(* 3#'* (+!',(* ( !$#+(" CH=CH2OHK $#373 #3#,(

,! 5"((" !$"'( ( 5"((" ,! !&!#'*. O* #"(%'* )(,!3 )!&,!& 3 )&%$(+ ,#

',&('"# !3 !&$(* *("4!+$!* 3#'* #* *#* 7#*!* (+#,#* *9( $9( ;(&$!* 6!

!"!* +9( *9( 5',(* !3 5# ATINS ! JONES 200K.

O* #"(%'* *9( ,'4',',(* !3 $&* "#**!* ,! #(&,( (3 ( +3!&( ,! &)(*

(&:+'(* "'#,(* #( 5$(3( ,! #&7(+( 6! (+$3 ( &)( OH. U3 5"((" )&'35&'(

$!3 # ;%&3"# RCH2OH !3 6! R )(,! *!& 6#"6!& &)(. U3 5"((" *!+,5&'(

$!3 # ;%&3"# R2CHOH ! 3 5"((" $!&'5&'( $!3 # ;%&3"# R =COH ATINS !

JONES 200K.

O* #"(%'* (3 3#**#* 3("!"#&!* )!6!+#* *9( "6',(* O* #"(%'* $3

)&!**9( ,! 4#)(& 3#'* 7#'# ,( 6! (* ',&(#&7(+!$(* ! 3#**# 3("!"#&

#)&('3#,#3!+$! '#". P(& !!3)"( ( !$#+(" ! "6',( +# $!3)!$ #37'!+$!

3#'* ( 7$#+( $!3 3#**# 3("!"#& 3#'(& ! 3 5* ATINS ! JONES 200K.


5/15

A 4("#$'"',#,! &!"#$'4#3!+$! 7#'# ,(* #"(%'* 3# 3#+';!*$#89( ,#* ;(&#*

,#* "'#8!* ,! ',&(+'(. A #)#',#,! ,! ;(&3#89( ,! "'#8!* ,! ',&(+'(

$#373 !)"'# # *("7'"',#,! !3 5# ,(* #"(%'* (3 3#**#* 3("!"#&!* 7#'#*

ATINS ! JONES 200K.

O )!$&%"!( (3( ;(+$! ,! !+!&'# ;(' !**!+'#" )# #+$'& ( ,!*!+4("4'3!+$(

'+,*$&'#" ,+$! ( *"( . A$* ,# *# ,!*$'"#89( ;'(+#,# )(,!*! (7$!&

45&'(* )&(,$(* ,!&'4#,(* ,! +,! '3)(&$:+'# !(+3'# 3#'* # ;Y( ,(

)!$&%"!( 6! #)&!*!+$# 3#'(& 4#"(& (3!&'#" # #*("'+# $')'#3!+$! 3# 3'*$

,! ',&(#&7(+!$(* *#$,(* 6! (+$3 ,! '+( # ('$( 5$(3(* ,! #&7(+( )(&

3(""# FELTRE 200?K.

U3 (3)(+!+$! )&!*!+$! !"*'4#3!+$! +# #*("'+# 7*'"!' 6! 3!&!!

,!*$#6! !*)!'#" ( !$#+(". S! )&'+')#" )#)!" #$#& (3( #+$',!$(+#+$! !3

*7*$'$'89( #( 37( $!$!$'"# 6! !*$5 *!+,( 7#+',( ,!4',( # *# !"!4#,#

$(',#,!. A 6#+$',#,! ,! !$#+(" )&!*!+$! +# #*("'+# ,!4! &!*)!'$#& (* "'3'$!*

!*$#7!"!',(* )!"# ANP A+'# N#'(+#" ,( P!$&%"!(K 6! *! $!(& ,!4! !*$#&

!+$&! 22 ! 2 !3 4("3!. W2X S!+,( #'+,# 6! ,! #(&,( (3 ( C(+&!**(

N#'(+#" # L!' F!,!" +. Y.2=/= &!"#3!+$# 6! # #*("'+# #,'$'4#,# ! (33

,!4! (+$!& 22,0 ,! 5"((" !$"'( #+',&( (37*$4!".

A ,!$!&3'+#89( ,( $!(& ,! !$#+(" +# #*("'+# ,!+$&! 45&'#* !'*$!+$!* # 3#'*

(33 # !$Y( (3 5# 6! (+!',# ! $'"'#,# (3( !)!&'3!+$(* !3

!*("#* ,( !+*'+( 3,'( (3 ( (7!$'4( ,! #)"'#& (+!'$(* &!"#'(+#,(* (3

3!,',#* 6#+$'$#$'4#* (3 ( $!(& !)&!**( !3 )(&!+$#!3 FELTRE 200?K.

A ,!+*',#,! ,!;'+!*! (3( ( 6('!+$! !+$&! # 3#**# ! ( 4("3! ,! 3

(&)( ( *!# )(,!*! ,'!& 6! # ,!+*',#,! 3!,! ( ,! (+!+$Y( ,!3#**# !3 ,!$!&3'+#,( 4("3!. A ,!+*',#,! )(,! *!& ,!$!&3'+#,# )!"# ;(&+!',#

)!"# !6#89( 1. D! #(&,( (3 ( S'*$!3# I+$!&+#'(+#" SIK # ,!+*',#,!

!)&!**# !3 [/3\ 3#* 3'$#* 4!!* !+(+$,# !)&!**# !3 /3\. Q#+,( *!

&!;!&! # 3# *7*$:+'# ) 3#'8# ! (3(+!# (3( !"!3!+$(* ( (3)(*$(*

63'(* # ,!+*',#,! #3#,# ,! ,!+*',#,! #7*("$# ( 3#**# !*)!;'#.

C#*( (+$&5&'( #3#,# *(3!+$! ,!+*',#,! ! &!)&!*!+$# # ,!+*',#,! 3,'# ,!

3 (&)( ( ,! 3# *7*$:+'# +9( (3(+!#.


6/15

A'+,# 6! ( ('+'( *!# 3 ,(* !"!3!+$(* )&!*!+$!* !3 3#'(& ;&!6+'#

+#* 3(""#* (&:+'#* +9( *! ,'*)! ,! +!+3 !+*#'( !*)!;'( ,'&!$( )# #

*# ',!+$';'#89( 6! #$!+,# #* #$!&*$'#* !;'#!* # 6! 3 !+*#'( ,! #+5"'*!

!"!3!+$#& 6#"'$#$'4# ;(&3#"3!+$! ,!4! *#$'*;#!&. A ',!+$';'#89( ,! ('+'( !3

3(""#* (&:+'#* +(&3#"3!+$! ;!'$# #$* ,# ',!+$';'#89( ,! &)(*

;+'(+#'* !3 6! !*$!# )&!*!+$! OH NO2 CO2H !$K. F+,#3!+$#,(

!+$&!$#+$( +# #)#',#,! ,! ((&,!+#89( ,(* )#&!* ,! !"$&(+* +9( "'#+$!*

)&!*!+$! +!*$!* &)(* )(**4!" !*$#7!"!!& 3 3$(,( 6! )!&3'$! 4!&';'#& #

)&!*!+8# ,! ('+'( !3 "6',(* (&:+'(*. O *( ,! '(,( (3( *(+,# ,#

)&!*!+8# ,! (3)(*$(* ('!+#,(* "6',(* 7#*!#,( +( (+!'3!+$( ,! 6!

!3 *("4!+$!* ('!+#,(* ( '(,( *! ,'**("4! (3 (& #*$#+#O '(,()&(4#4!"3!+$! ;(&3# 3 #,$( "'+!#& ,! $+*;!&+'# ,! #&# 6! ! #

("(Y( #*$#+#K. E*$! !+*#'( *% &!#"3!+$! 45"',( )# "6',(* )&(* !3 6!

*! '+"!3 (74'#3!+$! *%"',(* ;+,',(* APOSTILA DE ANALISE ORG]NICA

2011K.

O* $!&!* *'3)"!* *9( (3)(*$(* 3'$( )(( &!#$'4(* *!+,( )(& '**(

;&!6!+$!3!+$! *#,( (3( *("4!+$!* )# &!#8!* (&:+'#*. E"!* *9( 7#*$#+$!

&!*'*$!+$!* #( #$#6! ,! 7#*!*. ALLINGER !$ #" 1K.

R!#89( !+*#'( ,! I(,(

R!#89( !+*#'( ,! I(,(


7/15

U3 3'&(&'*$#" ,! '(,( ,'**("4',( !3 3# ($# ,! #3(*$ !3 3'&($7(

( )"## ,! $(6!. S7*$:+'#* (3 !$!&(5$(3(* )&(,!3 ("(Y( #*$#+#

!+6#+$( #"#+(* ! #"(!+#,(* )&(,!3 ("(Y( 4'("!$#. A&(35$'(* )&(,!3

("(Y( #4!&3!"#,#. P(,! *!& $'" (3)#& *# #3(*$ (3 )#,&!* (+,! (

!$#+(" "(&(;%&3'( ! $("!+( *9( %$'3#* ()8!* S&'+!& !$ #" 200?K.

2. OBJETIVOS

D!$!&3'+#89( ,( $!(& ,! 5"((" ,!+*',#,! ,# #*("'+# ! $!*$!* ,! ',!+$';'#89( ,!

&)(* ;+'(+#'*.

=. MATERIAIS E MTODOS

!.1 "#$%&'#'(

A3(*$ ,! #*("'+# ^# ,!*$'"#,# P&(4!$# ,! 100 3L (3 $#3)# P')!$# 4("3$&'# 10 3L

P

B#"#+8# #+#"$'# B6!& 100 3L C(+$# ($#* E*)5$"#* T7(* ,! !+*#'(• F!+("

N#;$("P#!$#3("

C"(&!$( ,! ;!&&( F!C"=K 17$#+("

27$#+(" 23!$'"2)&()#+("

!.2 M)$*+*(

D%$%&"',#-* +* $%*& +% /0**0 % +%,('+#+% +# #(*0',#

P&(!,'3!+$( 1_ #,''(+(*! 0 3L ,! 5# ,!*$'"#,# !3 3# )&(4!$# ,! 100 3L

!3 *!',# #,''(+(*! 0 3L ,! #*("'+# *(7&! # 5# ,!*$'"#,#. A'$(*! #

)&(4!$# ,!4',#3!+$! $#3)#,# )(& ,! *!+,(* ,!'( # )&(4!$# !3 &!)(*(

#7*("$( #$ # *!)#Y( ,! ;#*!* ! #+($#+,(*! #**'3 ( 4("3! ,# ;#*! #6(*#.


8/15

P&(!,'3!+$( 2_ D!$!&3'+(*! # ,!+*',#,! #$* ,# *!)#Y( ,! ;#*!* !+$&! #

#*("'+# ! # 5# ,!*$'"#,# 3!,'*! 6#+$#* 3L ,! ;#*! #6(*# (7$!4!*! !

)!*(*! ( 3!*3( (7$!+,( #**'3 # *# ,!+*',#,!

T%($% +% '+%,$'3'#-* +% &45*( 34,'*,#'(

F!+%'*_ #,''(+(*! !&# ,! 0 3 ,! 3 *%"',( ,!*(+!',( ( ($#* ,! 3

"'6',( ,!*(+!',( # 1 3L ,! 5# ,!*$'"#,# (+$',( !3 3 $7( ,! !+*#'( #'$(

# 3'*$ ,! 3(,( 6! ( 35'3( )(**4!" ,# *7*$:+'# *! ,'**("4!**! !3 5#.

A,''(+( # 3'*$ ($#* ,! "(&!$( ,! ;!&&( # 2.

A"(%'*_ ("((*! 2 3L ,( &!#!+$! ,! L#* !3 3 $7( ,! !+*#'( ! #&!*!+$(

$&* # 6#$&( ($#* ,( 23!$'"2)&()#+(". A'$(*! ( $7( ,! !+*#'( 4'(&(*#3!+$!! &!)!$'*! ( )&(!,'3!+$( )# 27$#+(" ! 17$#+(".

T%($% +% J*,%(

D'**("4!*! ,#* ($#* ,# #3(*$ # *!& #+#"'*#,# !3 ,! ($#* ,! #!$(+# )

! #,''(+(*! (3 #'$#89( ,! # ($#* ,# *("89( ,! 5',( &3'(.

6. RESULTADOS E DISCUSS7ES

DENSIDADE DA GASOLINA

D! #(&,( (3 M#&$'+* L()!* ! A+,,! 201=K *7*$:+'#* )("#&!* $!+,! #

,'**("4!& *7*$:+'#* )("#&!* ! #)("#&!* ,'**("4!&!3 #)("#&!* ( *!# *!3!"#+$!

$!+,! # ,'**("4!& ( *!3!"#+$!. S#7!+,( ,!**! (+!'$( 4!&';'(*! +# *("89( ,!#*("'+# # (3(!+!',#,! ,( 5"((" )# (3 # 5# )('* #37(* *9( *("8!*

)("#&!* ! #**'3 (7$!4!*! ,#* ;#*!* #*("'+# ! !$#+("5#.

P!"# $#7!"# 1 7#'( !*$5 )&!*!+$! (* 4#"(&!* ,! ,!+*',#,! ,K ,# *("89( ,! !$#+("

5# !3 ;+89( ,( $!(& ψ K ,! !$#+(".


9/15

TABELA 1 8 V#"(&!* ,! ,!+*',#,! ,K ,# *("89( ,! !$#+("5# !3 ;+89( ,(

$!(& ψ K ,! !$#+(".

9:;


10/15

TABELA 2 V#"(&!* ,! 4("3! ! 3#**#*.

V("3!

V etanol−água(g ) K

M#**#

M bequér( g) K

M#**#

M etanol−gasolina (g ) K

M#**#

M etalnol−água K

=0000 101? ?== ??

P# 6! ( 5""( ;(**! &!#"'#,( $'"'(*! # E6#89( 1_

μ= M etanol−água

V etanol−água E6#89( 1K

E+(+$&(*! ( 4#"(& !)!&'3!+$#" )# # ,!+*',#,! ,( !$#+(" '#" # 0?0 /3L

*7*$'$'+,( #**'3 +# E6#89( 2 # ,!+*',#,! !)!&'3!+$#" ,( !$#+(" )(,!*!

"(& ( 4#"(& ,! $!(& ,! !$#+(" +# *("89( ,! #*("'+#.

ψ = -451,89 + 452,31 E6#89( 2K

O+,! ψ ( $!(& ,! 5"((" # *!& !+(+$,( ! # ,!+*',#,! !+(+$,#

!)!&'3!+$#"3!+$! $!3*! 6! ψ = 25,72 (v /v ) .

D! #(&,( (3 ( C(+&!**( N#'(+#" # L!' F!,!" +. Y.2=/= &!"#3!+$# 6! #

#*("'+# #,'$'4#,# ! (33 ,!4! (+$!& 22,0 # 26 ,0 ,! 5"((" !$"'( #+',&(

(37*$4!" 4'*$( 6! ( 4#"(& !)!&'3!+$#" ;(' ,! 25,72 , ( *!# !+6#,*! #(

$!(& )!&3'$',( )(& "!'.

A 3'*$ ,! #*("'+# (3 5"((" *! ,5 3# 4! 6! !*$! #,'$'4( ('!+#,( 5"(("K

#3!+$# # ($#+#!3 ! &!, # !3'**9( ,! 3(+%',( ,! #&7(+( )# #

#$3(*;!. D'!+,( ,! 3# ;(&3# 63'# ( 6! ((&&! 6!

`...K !+6#+$( # #*("'+# ) 6#*! '3'*4!" +# 5# ( !$#+(" (3)"!$#3!+$! 3'*4!" +# #*("'+# ! +# 5# !3 $(,#* #* (+!+$!*.

Q#+,( ( !$#+(" !*$5 )&!*!+$! +# #*("'+# ! +# 5# )#&$''(+#*!)&!;!&!+'#"3!+$! ,!+$&( ,# ;#*! #6(*# #3!+$#+,( # *("7'"',#,! ,!


11/15

BTEa +# 5# ! &!,'+,( # $!+*9( '+$!&;#'#" ,# #*("'+#5#. O *'*$!3#;'+#" *!&'# (3)(*$( ,! 3# ;#*! ,! 5# (3 5"((" ! #"3# #*("'+#,'**("4',# ! 3# ;#*! ,! #*("'+# (3 5"((" ! 3 )(( ,! 5#,'**("4',#. C(3 3# )&()(&89( *;''!+$!3!+$! #"$# ,! !$#+(" !3 3

*'*$!3# # #*("'+# ! # 5# $(&+#3*! (3)"!$#3!+$! 3'*4!'* ! 3#;#*! +'# *!&5 ,!*!+4("4',#.b FERREIRA OLIVEIRA DUARTE 200?).K.

aA&+'3( 6! ,5 +(3! #( &)( ,! (3)(*$(* ;(&3#,(* )!"(* ',&(#&7(+!$(*.

TESTE DE IDENTIFICAÇÃO DE GRUPOS FUNCIONAIS

F%,@'(.

T!*$(*! #!$#3'+(;!+( )#!$#3("K ,'",( !3 H20 ;!+(" #6(*( ! +#;$(" !3

!$#+(" )('* !*$! )(**' 3# #,!'# )#&'#"3!+$! '+*("4!" !3 H2O #( &!#'& !*$!*

*("$(* !3 3 &!#!+$! ,! ',&%',( ,! *%,'( (7*!&4(*! 6! ,! '3!,'#$( +9(

(4! 3,#+8# ,! ("(Y( !*)!&(*! !3 &!)(*( #)%* 3 $!3)( ;(' )(**4!"

# )#&'#" 3,#+8# ,! ("(#89( #)!+#* ,( $7( ,! !+*#'( 6! (+$'+# +#;$(" !3

,!(&&+'# ,! 6! *7*$#+'#* ;!+%'#* &!#!3 (3

',&%',(* )&(,'+,( *("8!* ,! ;!+%',(* #* 6#'* *(;&!3 ;5'" (',#89( )(& #&,#+,( *("8!* ("(&',#* !"3!+$! 3#&&(+*K.

T!*$(*! #!$#3'+(;!+( )#!$#3("K ,'",( !3 H20 ;!+(" #6(*( ! +#;$(" !3

!$#+(" )('* !*$! )(**' 3# #,!'# )#&'#"3!+$! '+*("4!" !3 H2O (7*!&4(*!

3 #)#&!'3!+$( ,! 3# ("(Y( #" 3#&'+( 4'("!$# 4!&3!"( ##*$#+#,#

'+,'# # )&!*!+8# ,! ;!+(" ( 6! !4',!+'# # !'*$+'# ,! 3 (+ ,!

H!#6'*;!+(K;!&$( IIIK ,#,( )!"# *!'+$! &!#89(_

+¿

3−¿+6 H ¿

3+¿→ [ Fe (OAr )6 ]¿

6 ArOH + F e¿

Á0**'(.


12/15

^"(('* (3( !$#+(" 17$#+(" 27$#+("! !+!&'" C 5',( #*%&7'(K

*("89( #6(*#K $!3 *# "#**';'#89( ,!)!+,!+$! ,# )(*'89( ,# ',&('"# (3( #

*!'&_

Á0**'( 5&'"/&'*( c #)&!*!+$#3 *# ',&('"# "'#,# # #&7(+( +# !$&!3',#,! ,#

#,!'#. P(**'+,( 3 &)( #$!&*$'( c CH2OH.

Á0**'( (%4,+/&'*( c #)&!*!+$#3 *# ',&('"# +',# # #&7(+( *!+,5&'( ,#

#,!'#. P(**'+,( ( &)( #$!&*$'( c CHOH.

Á0**'( $%&'/&'*( c #)&!*!+$#3 *# ',&('"# "'#,# # #&7(+( $!&'5&'(. P(**'+,(

( &)( c COH.

P&','5#'( Á0**'(

M%$#,*0 5"((" 3!$"'(K_ ;%&3"# H=C d OH )&(,',( !3 !*#"# '+,*$&'#" #

)#&$'& ,! #&49( ! 5# *#,( (3( *("4!+$!* !3 3'$#* &!#8!* ! (3(

3#$&'#)&'3# !3 )("3!&(*.

G0'%&*0_ "6',( #&()(*( '+("(& ! #,('#,( (7$',( #$* ,! 3#

*#)(+';'#89( &!#89( 6! (&''+# *#79(K ,(* *$!&!* 6! (+*$'$!3 %"!(* !

(&,*. E3)&!#,( +# ;#7&'#89( ,! $'+$#* (*3$'(* ! +# )&!)#Y( ,!

+'$&("'!&'+# !)"(*'4(K.

E$#,*0 5"((" !$"'(K_ *#,( (3( *("4!+$! +# )&(,89( ,! 7!7',#* #"(%"'#*

+# )&!)#Y( ,! 5',( #$'( $!& $'+$#* )!&;3!* ! (3( (37*$4!" ,!

#$(3%4!'*.

E,(#'* +% A,'+&* C&"'*

T%($% +% J*,%(

O $!*$! 7#*!'#*! +# (',#89( ,! #"(%'* )&'35&'(* ! *!+,5&'(* #)#&!!+,('3!,'#$#3!+$! 3 )&!')'$#,( 4!&,! (+;'&3#+,( #**'3 # )&!*!+8# ,(* 3!*3(*

(3( )(,!3(* 4!& +# *!'+$! &!#89(_


13/15

O 5"((" )&!*!+$! +# ;("# ,! (&$!"9 ( 3!+$(" 6! $!3 # ;%&3"# 3("!"#&

C10H20O ! *# +(3!+"#$ (;''#" 2cI*()&()'"3!$'"'"(!#+1(" )(**' #

*!'+$! !*$&$ !4',!+'#+,( #**'3 *# ("(Y(.

O $!*$! ;(' &!#"'#,( (3 ( C& e "#+# #4!&3!"#,(K )# C& e= #" !*4!&,!#,(K.

D!*$! ;(&3# ;(' )(**4!" ,'*$'+'& (* 5"(('* 1f ! 2f ,(* =f (3 ( C&O=K.

A T#7!"# = 3(*$ (* &!*"$#,(* ,(* $!*$!* ;!'$(*_

TABELA = 8 R!*"$#,(* (7*!&4#,( )!"( $!*$! ,! J(+!* &3'(.

R%#%,$%( O(%&


14/15

A ;(+$! ,! (+* ,'&(3#$( ( ,'&(3#$( ,! )($5**'( 6! (* "'7! 6#+,(

,'**('#,( !3 5#. A '(+'#89( ,( 5',( *";&'( ;(&+!! (* (+* He +!!**5&'(* -

&!#89(. N!**! #*( *9( )&(,',(* !$#+#" (+* &(3( IIIK ! 5#. O* (+* )($5**'(

! *";#$( )&(4!+'!+$!* ,# ,'**('#89( ,( ,'&(3#$( ,! )($5**'( ! '(+'#89( ,(

5',( *";&'(K ;(&3#3 *";#$( ,! )($5**'(. g(+* *";#$( +$#3!+$! (3 (+* &(3(

IIIK ;(&3#3 *";#$( ,! &(3( IIIK '#" # &!#89( # *!'&_

O ,'&(3#$( ,! )($5**'( #)&!*!+$# ("(Y( #"#+#,#. Q#+,( !**# &!#89(

((&&! ( &(3( ,( ,'&(3#$( ,! )($5**'( &!,',( # &(3( IIIK +# ;(&3# ,!

*";#$( ,! &(3( IIIK c C& 2SO? c 6! )(**' ("(Y( 4!&,! ! # &(3( IIK +#

;(&3# ,! *";#$( ,! &(3( IIK c C&SO? c 6! #)&!*!+$# ("(Y( #"#,#.

. CONCLUSÃO

C(+"'*! # !;'5'# +# ,!$!&3'+#89( ,( $!(& ,! 5"((" +# #*("'+# #)!*#& ,!

!'*$'&!3 45&'(* 3$(,(* ,! 4!&';'#89( (* 6! +(* ;( )&()(*$(* +# )&5$'# *9(

$9( !;'#!* 6#+$( (* ($&(* $!+,( #**'3 4!',#,! !3 +(**(* &!*"$#,(*.

N(* $!*$!* ,! ',!+$';'#89( ,! &)(* ;+'(+#'* (+*!'3(* $!& 3 &!*"$#,(

)(*'$'4( ,';!&!+'#+,( ;!+%'* ! #"(%'* ! #**'3 (+*!'3(* $#373 ,';!&!+'#& (

5"((" $!&'5&'( *!+,5&'( ! )&'35&'(.

.REFERNCIAS

A$['+* P!$!&. P&'+)'(* ,! 63'#_ 6!*$'(+#+,( # 4',# 3(,!&+# ! ( 3!'(

#37'!+$! / P!$!& A$['+* L(&!$$# J(+!* $,89( R'#&,( B'# ,! A"!+#*$&(. c =.

!,. c P(&$( A"!&! _ B(([3#+ 200.

F!"$&! R'#&,( Q3'# / R'#&,( F!"$&!. c . !,. c S9( P#"( _ M(,!&+# 200?.

FERREIRA S"4'# M#&'# OLIVEIRA E4!&$(+ ,! DUARTE U&'!". C(3)(&$#3!+$( ,##*("'+# (3 !$#+(" E20K ! ,# #*("'+# ) #)%* # *'3"#89( ,! 3 4##3!+$(


15/15

!3 ("+#* ,! "#7($%&'(. G!(". USP S&. '!+$. S9( P#"( 4. ? +. 2 ($. 200? . D'*)(+4!" !3 h$$)_//))!!(.'.*).7&/*'!"(.))i*&')$*'j#&$$!$k)',S11Y?200?00020000k"+)$k+&3'*(. A!**(_ !3 02 +( 201

MARTINS C"5,'# R. LOPES l'"*(+ A. ANDRADE J#'"*(+ B. ,!. S("7'"',#,!,#* *7*$:+'#* (&:+'#*. 201=. D'*)(+4!" !3_ h$$)_//mmm.*'!"(.7&/*'!"(.))i)',S0100?0?2201=000Y0002k*&')$*'j#&$$!$. A!**(_ !3 02 +( 201

NACIONAL C(+&!**(. L!' Nn Y.2= ,! 2Y ,! ($7&( ,! 1=. D'*)(+4!" !3_h$$)_//mmm.)"#+#"$(.(4.7&/'4'"j0=/"!'*/LY2=.$3. A!**(_ !3 02 +( 201.

A)(*$'"# ,! A+5"'*! O&:+'# U+'4!&*',#,! U+'+&'( E*("# D! C'+'# ET!+("('# D6! ,! C#'#* 2011.

ALLINGER !$ #" QUgMICA ORG]NICA 2n !,'89( R'( ,! J#+!'&( RJ 1K.

S&'+!& R. L. !$ #" T! So*$!3#$' I,!+$';'#$'(+ (; O&#+' C(3)(+,* Y$ !,.J(+ l'"!o k S(+*_ H(7([!+ 200? ). =0Y

densidade da gasolina

Documents